I recently finished tech reviewing an excellent book on VB 2010: Professional Visual Basic 2010 and .NET 4 published by Wrox/Wiley. The book is written by a compendium of first-rate authors.
The book is full of code examples and covers a range of topics from the basics of the language and objects to WPF, Silverlight, ASP and Entity Framework. My favorite chapter was the one on Azure because it has some really good sample code that demystifies programming “in the cloud.”
If you write in VB, I would definitely recommend you pick up this book which you can do here.